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Hexafluoroisobutylene
3,3,3-Trifluoro-2(trifluoromethyl)-1-propene

Hexafluoroisobutylene is a specialty monomer useful for coatings and fluoropolymers. It is supplied by DuPont as a colorless, pressurized liquid.

Sales Specification
PropertyLimit
Hexafluoroisobutylene, wt. %99.5 min.
Hexafluoropropene, wt %0.5 max.
Acetone/hexafluoroisovalero lactone, wt % 0.3 max.
H/CH3-substituted hexafluoroisobutylene, wt % 0.5 max.
Trifluoromethane, wt %0.05 max.
Allene/pentadiene isomers, wt %0.2 max.
Oxygen, wt %0.02 max.
Perfluoroisobutylene, wt % not detected

Uses
Hexafluroisobutylene (HFIB) is a specialty monomer used in coatings and fluoropolymers, to produce materials with high temperature and chemical stability and good optical properties. In addition, HFIB can be used for blowing agents and refrigerants, and for specialty chemical applications.

Typical Physical Properties*
Property Value
CAS Name 3,3,3-Trifluoro-2(trifluoromethyl)-1-propene
CAS Number 382-10-5
Molecular formula C4H2F6
Molecular weight 164
Boiling Point 14.5 C (58.1 F)
Melting Point -111 C (232 F)
Volatiles, wt % 100
Form Pressurized liquid
Critical Temperature 156 C (313 F)
Liquid Density r(g/mL) = 0.614 + 212/T(K) (0-33 C [32-91 F])
Vapor Pressure log P (psia) = 5.574 - 1270/T(K) (14.5-72 C [58-162 F])
Solubility in Water 2.3 ´ 10-4 g/g water at 23 C (73 F)
*This table gives typical properties based on historical production performance. DuPont does not make any express or implied warranty that these products will continue to have these typical properties.

Handling
Hexafluoroisobutylene is supplied as a pressurized liquid, which is toxic by inhalation, and may cause irritation of the nose, throat and lungs. Protect against respiratory exposure. Skin contact may cause frostbite; wear appropriate gloves. Refer to the MSDS for additional handling information.

Packages
HFIB is available in pressurized cylinders of 0.45kg (1lb) and 1000kg (2.2M lb) net.

 

 

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Download the HFIB Product Bulletin for additional information

 
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